i would disjoin each machine prior to running dcpromo on the server. this should remove policy info, ect from the clients. you probably could just run dcpromo (only 1 server, yes) and that will remove active directory (and domain info) and you will be back to a member server.
As buddafish stated above, simply run DCPROMO to demote your Domain Controller back to a Member Server. (after you remove all of your PC's from the domain)
It works both ways,...running DCPROMO on a Member Server promotes it to a Domain Controller and running DCPROMO on a Domain Controller demotes it back to a Member Server.
to disjoin a pc, right click "my computer" ---> network identification tab --> properties --> you should see the domain name listed in the box. select the workgroup radio button, give it any name "testlab", ect.. and choose ok, ok, ok... and re-boot. the pc is no longer able to logon to the domain...
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