Are these files you're opening created in older versions of Office (doc, xls vs. docx, xlsx)??? If so, Office 2007 products open them in compatibility mode which seems to take 4 times as long to open. Once open, SAVE AS and save them as 2007 version.
You mention "a bootsrap error", what is the exact error that you are getting? Are you getting it during normal operation of Office, or only during some repair of Office?
Have you tried running your Office with all other programs prevented from running to see if you can isolate a cause?
310560 - How to Troubleshoot By Using the Msconfig Utility in Windows XP
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