Suppose you have 2 NETs in your company with no
physical connection
NET A:
net=192.168.1.0 NM=255.255.255.0 DG=192.168.1.251
NET B:
net=192.168.2.0 NM=255.255.255.0 DG=192.168.2.251
192.168.1.251 and 192.168.2.251 are 2 routers one for
each network
If you ping a PC of NET B from one of the NET A you see timeout.
The best way to understand this is to think your
Pc with 2 nics (also if it is not mandatory).
you wire nic 1 on Lan A and give IpAd = 192.168.1.100
you wire nic 2 on Lan B and give IpAd = 192.168.2.100
Now the 2 network are linked by your PC :
from your PC you can ping address of both net, but other PC
of NET A cannot still see PC of NET B.
In one PC of net A, you can add a another gateway putting the adress of your PC (192.168.1.100)
In one PC of net B, you can add a another gateway and you
can put the 2nd adress of your PC (192.168.2.100)
If you activate IP-Forwarding, (probably you have a NT4)
your PC can acts as router between networks.
If this is clear, think that the 2 networks can be on the
same lan ( just 1 hub whith machines on diff networks)
and your pc may have just 1 nic with 2 ip address.
bye