The SQL command to use is ALTER TABLE ADD|DROP CONSTRAINT , once you have created a table with Enterprise Manager u need to know the default constraint name, u can make use of sp_helpconstraint SP to get the constraint name, Correct me if i'm wrong there is no way you can change the default value of a column with a SINGLE SQL statement, the only way to do is drop and recreate the default constraint
See the example below
/*Create table with default value for column test1 to 0 */
BEGIN TRANSACTION
go
CREATE TABLE dbo.Table4
(
test1 int NULL
) ON [PRIMARY]
go
ALTER TABLE dbo.Table4 ADD CONSTRAINT
DF_Table4_test1 DEFAULT 0 FOR test1
go
--Change the Default value of column test1 to 4
BEGIN TRANSACTION
ALTER TABLE dbo.Table4
DROP CONSTRAINT DF_Table4_test1
go
ALTER TABLE dbo.Table4 ADD CONSTRAINT
DF_Table4_test1 DEFAULT 1 FOR test1
dbtech