Network admins have no business being in there at all when a dba is available. set everyone up correctly who should have access then remove builtin/administrators. Webmaster may be a different issue, but if your haveing that many problems with people making changes and not admiting it, revoke there ability to make structal changes and have all scripts sent to the dba to run on the production database. You can leave them as datareaders/datawriters so they can modify the actual data. If thats an issue to, just give read only privlages.
It sounds like the sql dba needs to take sole control. I had to do that when i arrived here.Everyone bitched and moaned when i told our director of it we needed to do this. Everyone is happier in the long run. They know its well taken care of and only developers have acccess to thier own databases, no one else. IF it was changed it was either them or me. And i have no reason to change thier stuff. We do have a backup person with admin abilities, but they have no knowledge of sqlserver and know not to touch it. They are just there in case something needs to be done but im not around. The developers have to show them what they need to do. And he keeps a list of everything that he does for it to give to me in case they try to get sneaky.
If you are the dba, talk to your top IT/IS person and tell him the issues and what needs to be done.