I don't think so. Heres what we did, but maybe someone else knows a better way.
We created a separate user profile (add 1 or something to the existing profile name). Copy the user's existing profile, add it to the admin group, and then set the logon hours for the new profile from noon to 4:00 PM.
The user has to log on using the new profile to have the admin permissions. They can't log on before the designated time and after the set hours they would automatically be disconnected.
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