Actually, logon scripts are executed in the security context of Local System.
In any case, two choices:
1. You can use WMI scripting:
'Beginning Of the Script
On Error Resume Next
'get main objects/variables
Set ws = WScript.CreateObject ( "WScript.Shell" )
compname = ws.ExpandEnvironmentStrings ( "%COMPUTERNAME%" )
Set adGrp = GetObject ( "WinNT://" & compname & "/Administrators,group" )
'add
domain groups to local admin group: example
'example domain group is Domain Administrators:
adGrp.Add ( "WinNT://Main/Domain Admins,group" )
'
'
'add
domain user to local admin group
'example domain user is jjones
adGrp.Add ( "WinNT://Main/jjones,user" )
'End of the Script
2. Use NET LOCALGROUP
Example: >net localgroup "administrators" "bcastner\power users" /add