What are you trying to achieve with these options can you give some more details?
If you have set your Power Options to be "Always On" you can still enter Standby (manually) even if you have selected the "Never" option for Standby.
Are you trying to prevent entering Standby automatically during business hours and allow it to enter Standby automatically out of hours?
See what is available with Powercfg, I'm not sure myself whether you can do much with it and Standy having never tried it. This first link also points to Kelly Theriot's site where you might find a script for Standby that possibly you can use with Task Scheduler, again I'm not sure if it is of any use, but it might be worth looking at.
Powercfg.exe is designed to work on the Windows Server 2003 family. It may work on other operating systems, such as Windows 2000; however, Microsoft does not guarantee that it will work on other operating systems and does not support its use. If you use this tool on other operating systems, use it at your own risk."
So say Microsoft, but I have checked XP Home and XP Pro systems I have, and both have Powercfg included as a System32 exe.
The Powercfg.exe tool is included with the following operating systems: • Microsoft Windows XP with Service Pack 2 (SP2)
• Microsoft Windows Server 2003
The Powercfg.exe tool is not supported in Windows 2000
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