Wrox is a great choice.
It also depends on what language you are interested in, but here are some good titles.
Level one books
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"Beginning VB.NET"
"Beginning C#"
"Beginning ASP.NET using VB.NET"
"Beginning ASP.NET using C#"
Level two books
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"Professional VB.NET"
"Professional C#" (I'm currently reading this one)
"Professional ASP.NET"
Reference Books
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"ADO.NET Programmer's Reference"
A book I have read and really loved was from Microsoft Press:
"Building Web Solutions with ASP.NET and ADO.NET"
Author: Dino Esposito
Overall the Wrox books are awsome, and I will try to to write some reviews of come of the above mentioned books in this forum.
Hope this Helps and good luck!