Yes, basically MFC is just an extensive library of classes made by Microsoft that handle all of the details in displaying graphics, creating windows, handleing events, and more. You can acctually see these classes in VisualStudio if you wanted, it all starts in AfxWin.h I believe.
The book I used was Introduction to MFC Programming by Richard M. Jones. It was ok, but keep an eye out for something that you think will go along with your style of learning. When you first start with MFC, unfortunately, you don't get to see graphics instantly. You have to familiarize youself with classes like CPoint, CString, and other key MFC classes. Then you finally begin to build your windows applications like Note Pad that handles text and other simple graphics. Eventually you will move on to bitmaps and simple animations.
-Bones