I would have though not with the table itself, but perhaps PHV's idea, using a byte field and a validation rule of <5 (0-4), or here's another (clumsy) workaround.
Create an extra table, with, for instance a numeric primary key, and a text field. Enter
1 - USER1
2 - USER2
3 - USER3
4 - USER4
5 - USER5
Then relate it one to one with your user table. I e, primary key of the user table, also numeric, then with both having unique indexes, you shouldn't be able to enter more than the same number of records in your table.
Roy-Vidar