DW has a Great "Tutorials" (and Using Dreamweaver) section...start slow...do simple things and ones you get the understanding to what changes do what....exploring and learning HTML will be a breaze.
Start with learning things such as "images & HTML, page sizes, browser support and differences, using tables-cells to design HTML pages,linking documents/pages, font sizes,colors etc..... much like you would go about learning to how Create a "nicely styled" letter in MS Word.
Rome was not built in a day....but who is to say that the Idea of it wasn't ;-)
All the best!
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