Yes, I do it all the time, but if the Access application goes down...
I was going to just install an Outlook client on the server that runs the Access email alert program, and CC all the emails to it, and if it did not get a CC within a certain time frame, it would send an email to the admins from the Outlook client, but this has turned out to be something that Outlook can't do very well. I've decided to take the path of writing a Services app in VB.net that monitors the date and time on a text file I've programmed the email server to spit out every hour, the Service app will use System.net.mail to send the "system down" alert.