Promoting to a DC on its own doesn't really require much more space, as you surmise it is AD and login scripts, group policies that take up the room.
I suggest you look at the sizes of the \%systemroot%\ntds (which contains NTDS.DIT which is the AD database) and \%systemroot%\sysvol folders on an existing DC and see how big they are.
You can get dcpromo to put the NTDS folder on a different drive. Not sure if you can move sysvol.
If this is going to be the only DC in the domain then AD won't be too large to start with but can grow quite rapidly.
You sure you can't rebuild the server with a bigger C:?
Neill