Yep no problem. I am currently doing just that.
All you need to do is set up MySQL, PHP and Apache on your Windows PC. This will give you the ability to develop your application in a localhopst environment or directly from the server.
I would also suggest you grab the DBTools application which you can use in Windows to manipulate,create and change the structures and queries in a windows GUI interface. This app can be found from a link on the MySQL site.
Good Luck.
Spijker