XDSL and ethernet are completely different types of circuits.
DSL is available in many flavors and is often just referred to as XDSL where you replace X with whatever flavor you want (ADSL, HDSL, etc). Generally the ISP has a device called a DSLAM (Digital Subscruber Line Access Multiplexer) at the Telco Central Office and the provides you a DSL 'modem' (not really a modem, modems convert digital data to analog data MODulatorDEModulator, the DSL equivelant is actually an ATU-R but often referred to a modem). Additionally, depending on the type of service, you may get a filter that filters out the high pitched digital noise after your 'modem' gets it, allowing you to use the lower frequencies of the single pair circuit for normal voice use.
POE (power over ethernet) refers to using a spare pair (ore more) in the 4 pair cat5 ethernet circuit to provide power to a piece of remote equipment. Generally this is used to power small switches, wireless access points, etc. All that is done here is an unused pair gets a voltage dropped on it, and we pick it up at the other end and power a device with it.
Hope that explains it, I'm honestly trying not to get too complicated with it.
Good Luck!
It is only my opinion, based on my experience and education...I am always willing to learn, educate me!
Daron J. Wilson, RCDD
daron.wilson@lhmorris.com