One thing you can do is to take a flat screwdriver and touch it 2 of the pins until the computer boots, that way you will find the power\on pins. From that you can pretty well figure it out after that. That is one way of doing it.
I copied that from above. Its basically in agreement with what Edfair said, the trial and error method is fairly safe. I can tell you that i have done this with probably somewhere between 50 and 100 motherboards. To the point where when i am taking a motherboard out of the case, i only give the connector area a quick look and try and remember, instead of writing it down. The reason is that the power\on is easy to find and the rest follow suit pretty easily. Never had a problem with shorting, arcing, etc, they are all protected. At least the front panel connectors, that is, cant say that blanket statement for everything. And one can get in trouble with certain usb connections where the person has a group of wires to connect to usb pins on a motherboard as some differ, there are at least 2 different standards there. But i dont even think you will run into that on your motherboard, so not to worry about it.
I,too, have read about booting without the cpu, i just never bothered to try it.
Have you got your front panel connectors all set up?
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