Exmerge will not work on corrupted mail, a lot of errors I have seen have been with corruption. The Service Account is the account that you are using to start the "Services" for Exchange. As far as the directory goes, I don't think it matters. Good luck.
ND, what I would do is export the Mailboxes from the server to a CSV file (Admin Program). Then create the distribution list you want for this server. (I would suggest using the server name) for example if the server was named MSXSvr1, name the Distribution list MSXSvr1. Once that is created...
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