Here's a tutorial that might help you: http://teom.coningham.net/psp-x/greyscale-and-color

Cut the eyes out of the coloured picture using the freehand tool. You will probably need to zoom in to do this. Save the eyes as a seperate file. Next convert the coloured image to grey scale. Now paste in the eyes over the grey image. Done.
Adrian.

No need to use a different file, just copy and paste them as a new layer onto the same file. Then just make the bottom layer B/W.


 

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Ignorance is not necessarily Bliss, case in point:
Unknown has caused an Unknown Error on Unknown and must be shutdown to prevent damage to Unknown.  

No need to copy and paste them either - just select them and then pick "promote to layer" from the selection menu.

Or - for another way to do it - duplicate the whole image as a new layer, then convert this new layer to black and white. You can then use the eraser tool to rub out the black & white layer and allow the coloured layer to show through from behind.

You should be able to find more detailed tutorials if you Google for "selective color" or "selective desaturation" (many might be for Photoshop, but will often apply just as well to PSP)

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