I'm not sure. It depends on the root of the problem you are having with VSS. If it's really a problem with the database state, that might help, but I suspect that it's more of a problem with VSS and specifically with the Exchange VSS Writer, so in that case, dismounting and remounting wouldn't help much.
From the command-line on that server, run "vssadmin list writers" and see what state the Exchange writer is in.
Also, make sure that the drive that the Exchange database is on isn't configured to create ShadowCopies during the same time window that the backup is supposed to run during.
If you see VSS errors in the logs that refer to timeouts, and you've already looked into ShadowCopy creation, then you might want to increase the VSS timeout from 10 minutets to 20 minutes to give certain snapshotting processes more time to complete.
You can manually extend the VSS timeout by editing/creating the following registry key:
HKLM\Software\Microsoft\Windows NT\CurrentVersion\SPP\CreateTimeout
This value is in milliseconds, 20mins equal 1200000 milliseconds.
Dave Shackelford
ThirdTier.net