If you haven't come up with a solution yet, here are some good links that will just about exhaustively cover RAID setups.
Both of these appear a bit simplistic, but once you getting diggin, you find these are both very "deep" leveled web sites.
And of course, there is always Wikipedia:
Although these won't tell you which system setup is best, it does give you a good foundation of what you want to do.
My personal reccomendation, since cost is of no concern, go with SCSI and skip the SATA stuff. I have had good luck with Highpoint controllers for both SCSI and SATA RAID's. Depending on what your application will be with this setup, RAID 5 has proven itself over time, and unless you are specifically doing some specialized application (like video editing or something else) this will offer the best performance bang for the buck with redundancy capabilities.
One last bit of personal reccomendation - overbuy the size and performance of what you think you will need. As with most circumstances, once a system is in place, people find a reason to change the nature of its scope, and things get "small" quickly. Also, if you go SCSI, go for the 15K drives. Lastly, buy AT LEAST one extra HDD. It seems no matter how mainstream the drives are when you buy them, 6 months later you can't find the exact duplicate drive to rebuild a crashed array. My personal preference is to buy a few extra drives and stoer them on a shelf so that the array can continual be rebuilt while awaiting RMA's, special orders, etc.