Looking at these three lines, it looks like you have an ip address problem.
ip address outside 66.40.203.54 255.255.255.240
access-list smtp permit tcp any host 66.40.203.54 eq smtp
static (inside,outside) 66.40.203.54 10.10.10.1 netmask 255.255.255.255 0 0
from the outside IP address line, it appears you have the 66.40.203.48 to 66.40.203.64 ip addresses inclusive.
However, you've tried to set the static IP address of your mail server to the same IP address as your pix outside interface. You CAN do this, but to do so, IIRC, you are supposed to use the word interface like this:
static (inside, outside) tcp interface smtp 10.10.10.1 smtp
What I'd recommend (unless you have IP address problems) is changing it like this:
ip address outside 66.40.203.54 255.255.255.240
access-list smtp permit tcp any host 66.40.203.55 eq smtp
static (inside,outside) 66.40.203.55 10.10.10.1 netmask 255.255.255.255 0 0