I've never done it, but I would start by firstly looking at using VBA code & referencing MAPI objects to see if I could get to it that way, or if you have Active Directory there are plenty of VBS script examples out there on retrieving information such as email addresses from AD. However I am not sure whether this would get addresses for people external to your firm. Alternatively if you have access to the necessary contacts folder you could use Outlook's Import & export function and use that to export it directly into Excel.
Maybe quite not the answer you were hoping for, but I hope this gives this thread a start with other people being able to add more detailed info.
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