Hey Buddy,
As you have a null modem cable I assume you want to connect two computers together so that they talk to each other. A null modem cable (or crossover cable - which I think is just different terminology for the same thing) will achieve this. The connector types can be different (they will be the same on both ends but can be in different form E.g. 9 pin or RJ45 etc).
Each connector end has a transmit and recieve pin (among others). What a null modem cable does is cross the transmit and recieve pins between the ends so that transmit sends to recieve. If you didn't do this you would have an ordinary straight through cable. This has no apparent use (to my knowledge) in 9 pin serial form but in RJ45 it can be used to connect a computer to a network connection point (otherwise known as a patch lead). RJ45 is the connector type you get on network cards (kinda like your phone). So, as an example, you could connect two PC's together via their network cards with a RJ45, null modem cable. You want to connect them via serial put the same applies. Please excuse the crude diagrams:
Patch Lead (Straight Through)
End1 End2
1 *************************** 1
T *************************** T
3 *************************** 3
R *************************** R
.
.
9 *************************** 9
Null Modem (Crossover)
End1 End2
1 *************************** 1
T --->--\ /----<- T
3 *********/---<---->--\********* 3
R ---<--/ \-->--- R
4 *************************** 4
5 *************************** 5
.
.
9 *************************** 9
HTH
R