[1] I suppose this is a typo.
><xsl:value-of select="lower-case($Freq"/>
[tt]<xsl:value-of select="lower-case($Freq[red])[/red]"/>[/tt]
[2] Then I suppose you know very well lower-case is xslt2 function and you use the xslt2-aware application.
[2.1] If $Freq sequence contains only one item, there should not be a problem.
[2.2] If $Freq contains more than one item, you have a problem. You've to zoom into a particular item, say, item 1.
[tt]<xsl:value-of select="lower-case($Freq[1])"/>[/tt]
then you should be fine.