As I said, you can set the root password any time from the hscroot user, but root login (and su root / su -) are disabled.
If the root user does not exist you can create it and set the password from the hscroot login.
Same goes for the hscpe user.
Once you have the root user and password, and the hscpe user and password setup then you need to login as hscpe, then run the pesh command and enter the IBM supplied, date specific, password to get to the pe shell, then you can su - or su root and enter the root password and you are root.
Sorry if that wasn't clear before.