no can do in AIX I'm afraid...
either delete and recreate, but keep the uid the same and then afterwards do all the changes to the user again (backup copy of shadow passwd, user, limits, ... files is a prereq)
or edit all files /etc/passwd /etc/security/passwd /etc/group /etc/security/group /etc/security/user /etc/security/limits ... manually.
HTH,
p5wizard