Probably the most noticable difference may be that bandwidth, and the fact that all four pairs are tested in 5E certification.
For Cat5 to pass a certification test it must send data down one pair and compare (listen) on all three other pairs. Formerly we only had to send data down one pair on Cat5 and listen on the other data pair, and get favorable results.
While the bandwidth for Cat5e may be up to 350 Mhz, it is only required to be tested at 100 Mhz for certification. The extra headroom there is what makes the cable more appealing for new technologies as they come along.
Also, according to the new revisions of the EIA/TIA standards, Cat5 is not longer an accepted media for new data installations, Cat5e is the minimum.
Good Luck
It is only my opinion, based on my experience and education...I am always willing to learn, educate me!
Daron J. Wilson, RCDD
daron.wilson@lhmorris.com