First, make sure the VPN connection is good and rule out addressing problems there. Start the VPN connection. Once it is established, right click on the icon on the task bar for the VPN connection and select 'status'. If you don't have the icon on the taskbar, open Network and Dialup connections and right click on the VPN connection there and select 'status'.
Once the status box is up, click on the details tab. Should have a server IP address and a client IP address. You should be able to ping both of these. If not, routing is not the problem.
Assuming that goes well, routing is the most likely problem, so open a command window. Type the following:
ROUTE ADD xxx.xxx.xxx.xxx 255.255.255.0 xxx.xxx.xxx.xxx
Replace the first set of xxx's with the network address of the remote network you are trying to reach. The 255.255.255.0 is the subnet mask of the remote network, I assumed the 255.255.255.0, you might need to adjust to match the configuration of the remote network. Replace the second set of xxx's with the client VPN IP you found in the status box earlier.
If you don't get an error, all is well and you should be able to reach the remote network.
The route will last as long as the VPN connection. If you take it down, the route will go away. If you get the same VPN address each time you connect, you can make the route stay by adding /p to the command.