You can use access list to deny the trafic to msn messenger.
Use netstat -n commnad to find out which port MSN messenger works. You can block that port or that IP address.
Make an extended access list: (the number 110 can be anything between 100 and 900 I beleive-not sure about 900 though, standard lists number till 99)
access-list 110 deny ip 152.232.x.x 0.0.0.0 any any eq 569
then put the access list on a port. the "eq 569" specifies the port. I could be a bit off on this (been a while) but I'm 100% sure you have to look up on how to configure extended ACL's
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