Some links which might be useful?
Cannot move or rename the Documents and Settings folder
How to Change the Default Location of the My Documents Folder
Program Files Directory on a different Drive from Windows
thread779-951874
A junction point (also known as a reparse point) is a technology for a folder to be grafted into another folder on the same local computer.
Junction Link Magic
Using Folder Redirector utility to redirect special folders in Windows XP
Moving Docs/Settings folder in windows xp pro
thread779-763308
"For all Documents and Settings.
The only safe and sure way of doing it is to use SysPrep before installing XP and specifying the location.
Alternativly you can use the TweakUI software from the microsoft website to relocate specific special folders, however this does not always work i have found.
Greg Palmer"
Relocating Hard Drive Capacity and File Compression
thread779-939540
ntfs back to fat32
thread779-918806
NTFSDOS.EXE is a file system driver for DOS/Windows
that is able to recognize and mount NTFS drives for transparent access. It makes NTFS drives appear indistinguishable from standard FAT drives, providing the ability to navigate, view and execute programs on them from DOS or from Windows, including from the Windows 3.1 File
Manager and Windows 95 Explorer.
The latest version of NTFSDOS can be found at
A full read/write version of NTFSDOS is available in the form of NTFSDOS Professional (also ERD Commander)
These write versions are not cheap.