I have had a similiar requirement, with a few bad users. What I did was use a OU (For the offending department's users) with a policy that turned on and utilised IE's Content Advisor . It was a little work identifying all the legal websites (About 30 of them). It works well, but my environment...
Goto Control Panel -> Mail
Double Click on 'Personal Folders'
Take note of the path where the PST is located.
Ensure that Outlook is closed and move the file to your back up server.
Go back to Control Panel -> Mail
Remove 'Personal Folders'
Click on 'Add'
Select 'Personal Folders'
Browse to the...
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